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N,N,N ,N -Tetramethyl-N,N -bis(sulfo)ethane-1,2- Diaminium Mesylate ‎as a Highly Effective and Dual-functional Catalyst for the Synthesis of 1-Thioamidoalkyl-2-naphthols

عنوان مقاله: N,N,N ,N -Tetramethyl-N,N -bis(sulfo)ethane-1,2- Diaminium Mesylate ‎as a Highly Effective and Dual-functional Catalyst for the Synthesis of 1-Thioamidoalkyl-2-naphthols
شناسه ملی مقاله: JR_CHM-4-4_003
منتشر شده در شماره 4 دوره 4 فصل در سال 1399
مشخصات نویسندگان مقاله:

Navid Irannejad-Gheshlaghchaei - Department of Chemistry, Payame Noor University, P.O. Box ۱۹۳۹۵-۳۶۹۷, Tehran, Iran‎
Abdolkarim Zare - Department of Chemistry, Payame Noor University, PO BOX ۱۹۳۹۵-۳۶۹۷, Tehran, Iran
Alireza Banaei - Department of Chemistry, Payame Noor University, P.O. Box ۱۹۳۹۵-۳۶۹۷, Tehran, Iran‎
Hamideh Kaveh - Department of Chemistry, Payame Noor University, P.O. Box ۱۹۳۹۵-۳۶۹۷, Tehran, Iran‎

خلاصه مقاله:
N,N,N ,N -tetramethyl-N,N -bis(sulfo)ethane-1,2-diaminium mesylate ‎‎([TMBSED][Oms]2) is ‎used as a highly efficient and dual-functional catalyst for the one-pot multi-component ‎condensation of 2-naphthol with arylaldehydes and thioacetamide under green, mild (70 °C), ‎and solvent-free conditions. In this reaction, 1-thioamidoalkyl-2-naphthols are produced in ‎high to excellent yields and in relatively short reaction times. In this reaction, products ‎are identified by analysis of its 1H NMR, 13C NMR, and FT-IR data.‎ Moreover, a plausible mechanism based on dual-functionality of the catalyst was proposed.

کلمات کلیدی:
N,N,N ,N -tetramethyl-N,N -bis(sulfo)ethane-1,2-diaminium mesylate ‎‎([TMBSED][Oms]2)‎, ‎Thioacetamide, 1-Thioamidoalkyl-2-naphthol, Multi-component ‎reaction, Dicationic ionic liquid, Dual-functional ‎catalyst.‎

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/1032183/