N,N,N ,N -Tetramethyl-N,N -bis(sulfo)ethane-1,2- Diaminium Mesylate as a Highly Effective and Dual-functional Catalyst for the Synthesis of 1-Thioamidoalkyl-2-naphthols
عنوان مقاله: N,N,N ,N -Tetramethyl-N,N -bis(sulfo)ethane-1,2- Diaminium Mesylate as a Highly Effective and Dual-functional Catalyst for the Synthesis of 1-Thioamidoalkyl-2-naphthols
شناسه ملی مقاله: JR_CHM-4-4_003
منتشر شده در شماره 4 دوره 4 فصل در سال 1399
شناسه ملی مقاله: JR_CHM-4-4_003
منتشر شده در شماره 4 دوره 4 فصل در سال 1399
مشخصات نویسندگان مقاله:
Navid Irannejad-Gheshlaghchaei - Department of Chemistry, Payame Noor University, P.O. Box ۱۹۳۹۵-۳۶۹۷, Tehran, Iran
Abdolkarim Zare - Department of Chemistry, Payame Noor University, PO BOX ۱۹۳۹۵-۳۶۹۷, Tehran, Iran
Alireza Banaei - Department of Chemistry, Payame Noor University, P.O. Box ۱۹۳۹۵-۳۶۹۷, Tehran, Iran
Hamideh Kaveh - Department of Chemistry, Payame Noor University, P.O. Box ۱۹۳۹۵-۳۶۹۷, Tehran, Iran
خلاصه مقاله:
Navid Irannejad-Gheshlaghchaei - Department of Chemistry, Payame Noor University, P.O. Box ۱۹۳۹۵-۳۶۹۷, Tehran, Iran
Abdolkarim Zare - Department of Chemistry, Payame Noor University, PO BOX ۱۹۳۹۵-۳۶۹۷, Tehran, Iran
Alireza Banaei - Department of Chemistry, Payame Noor University, P.O. Box ۱۹۳۹۵-۳۶۹۷, Tehran, Iran
Hamideh Kaveh - Department of Chemistry, Payame Noor University, P.O. Box ۱۹۳۹۵-۳۶۹۷, Tehran, Iran
N,N,N ,N -tetramethyl-N,N -bis(sulfo)ethane-1,2-diaminium mesylate ([TMBSED][Oms]2) is used as a highly efficient and dual-functional catalyst for the one-pot multi-component condensation of 2-naphthol with arylaldehydes and thioacetamide under green, mild (70 °C), and solvent-free conditions. In this reaction, 1-thioamidoalkyl-2-naphthols are produced in high to excellent yields and in relatively short reaction times. In this reaction, products are identified by analysis of its 1H NMR, 13C NMR, and FT-IR data. Moreover, a plausible mechanism based on dual-functionality of the catalyst was proposed.
کلمات کلیدی: N,N,N ,N -tetramethyl-N,N -bis(sulfo)ethane-1,2-diaminium mesylate ([TMBSED][Oms]2), Thioacetamide, 1-Thioamidoalkyl-2-naphthol, Multi-component reaction, Dicationic ionic liquid, Dual-functional catalyst.
صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/1032183/