Synthesis of composite proton exchange membrane made of the sulfonated metal-organic framework and sulfonated polymer

سال انتشار: 1399
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 299

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شناسه ملی سند علمی:

ICNNA01_122

تاریخ نمایه سازی: 21 دی 1399

چکیده مقاله:

In this study, octahedral crystal MIL100(Fe) is synthesized via hydrothermal reaction. It is then functionalized with sulfonic acid groups using chlorosulfonic acid in 1,2-dichloroethane at 25°C. The sulfonated MIL100(Fe) is homogenously incorporated into the sulfonated polysulfone (SPSU) matrix to prepare hybrid membranes. The performance of the hybrid membrane is evaluated by proton conductivity. The proton conductivity of the hybrid membrane increased to 3.82 mS cm-1 at room temperature and 100% RH, which is 75% higher than that of the pristine membrane. The increment of proton conductivity is attributed to providing sulfonic acid groups, forming additional proton -transport pathways at the interfaces of polymer and MOF, and constructing hydrogen-bonded networks for proton conduction.

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نویسندگان

Bita Roshanravan

Department of Environmental Science, Faculty of Natural Resources, Tarbiat Modares University, Iran

Habibollah Younesi

Department of Environmental Science, Faculty of Natural Resources, Tarbiat Modares University, Iran

Sang-Hyun Pyo

Department of Chemistry, Faculty of Engineering, Lund University, Sweden

Mahdi Abdollahi

Department of Polymer Engineering, Faculty of Chemical Engineering, Tarbiat Modares University, Iran