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Design and synthesis of metal-organic frameworks of Cu3(BTC)2 microbelts for waste-free green oxidation of sulfides

عنوان مقاله: Design and synthesis of metal-organic frameworks of Cu3(BTC)2 microbelts for waste-free green oxidation of sulfides
شناسه ملی مقاله: ISOC27_088
منتشر شده در بیست و هفتمین کنفرانس شیمی آلی ایران در سال 1398
مشخصات نویسندگان مقاله:

Saeed Ghasemi Laki - Organic and Nano Group (ONG), Department of Chemistry, Faculty of Science, University of Maragheh, PO Box ۵۵۱۸۱-۸۳۱۱۱.
Hassan Alamgholiloo - Organic and Nano Group (ONG), Department of Chemistry, Faculty of Science, University of Maragheh, PO Box ۵۵۱۸۱-۸۳۱۱۱.Department of Organic Chemistry, Faculty of Chemistry, Urmia University, Urmia, Iran.
Sadegh Rostamnia - Organic and Nano Group (ONG), Department of Chemistry, Faculty of Science, University of Maragheh, PO Box ۵۵۱۸۱-۸۳۱۱۱.

خلاصه مقاله:
Metal oganic frameworks (MOFs) as porous coordination polymers are nanoporous materials prepared using the well-established principles of coordination chemistry [1, 2]. MOF-based structures demonstrate various advantages such as having high surface areas and simplicity of processability, and being tuneable and stable alternative materials [2, 3]. Herein, we report the synthesis of open metal site MOFs of Cu3(BTC)2 with microbelt morphology and a study of the catalytic oxidation of organic sulfides Figure 1. The proposed catalyst was found to be an efficient, selective and waste-free green heterogeneous co-catalyst for the green H2O2 catalytic oxidation of sulfides.

کلمات کلیدی:
Open metal site MOFs; Cu3(BTC)2, Microbelts (MBs), sulfide oxidation,

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/1163896/