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ZnFe2O4/MnFe2O4 incorporated in NaY zeolite: Facile fabrication and application of novel designed nanocomposite catalyst for the detoxification of sulfur mustard agent simulant

عنوان مقاله: ZnFe2O4/MnFe2O4 incorporated in NaY zeolite: Facile fabrication and application of novel designed nanocomposite catalyst for the detoxification of sulfur mustard agent simulant
شناسه ملی مقاله: CESACONF01_018
منتشر شده در اولین کنفرانس بین المللی پژوهش در علوم مهندسی و علوم کاربردی در سال 1399
مشخصات نویسندگان مقاله:

Meysam Sadeghi - Department of Chemistry, Lorestan University, Khorramabad, Iran
Sina Yekta - Department of Chemistry, Qaemshahr Branch Islamic Azad University Qaemshahr, Iran
Mohammad Azimzadeh - Department of Chemistry, Islamshahr Branch Islamic Azad University Islamshahr, Iran
Mohammad Mahmoudi Alemi - Department of Chemistry, Golestan University Gorgan, Iran
Pourya Naji - Department of Food Science and Technology, Mahallat Branch Islamic Azad University Mahallat, Iran
Pourya Zarshenas - Faculty of Chemistry & Petroleum Sciences Shahid Beheshti University Tehran, Iran

خلاصه مقاله:
In this work, ZnFe2O4/MnFe2O4 nanoparticles were successfully incorporated in NaY zeolite via the ultrasonic-assisted hydrothermal method to obtain the novel ZnFe2O4/MnFe2O4@NaY nanocomposite catalyst and subsequently characterized by FE-SEM, EDX, FTIR, XRD, AFM and VSM techniques. Then, the ZnFe2O4/MnFe2O4@NaY nanocomposite catalyst performance for the detoxification of sulfur mustard agent simulant 2-chloroethyl phenyl sulfide (2-CEPS) was evaluated by applying GC-FID analysis. The GC-FID achieved data displayed that this agent simulant was completely detoxified over the ZnFe2O4/MnFe2O4@NaY nanocomposite surface in n-octane solvent after contact time of 15 min. The both hydrolysis and elimination products namely 2-hydroxyl ethyl phenyl sulfide (2-HEPS) and phenyl vinyl sulfide (PVS) from 2-CEPS molecule were also identified by GCMS analysis, respectively.

کلمات کلیدی:
ZnFe2O4/MnFe2O4@NaY, zeolite, nanocomposite, 2-CEPS,detoxification, hydrolysis, elimination.

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/1172021/