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Microporous membrane formation via thermally induced phase separation: Effect of temperature and evaporation time on membrane morphology

عنوان مقاله: Microporous membrane formation via thermally induced phase separation: Effect of temperature and evaporation time on membrane morphology
شناسه ملی مقاله: PPSRC2011_254
منتشر شده در کنفرانس بین المللی فرآورش پلیمرها در سال 1390
مشخصات نویسندگان مقاله:

Majid Pirali Hamedani - School of Chemical Engineering, College of Engineering, University of Tehran, P.O. Box:۱۱۱۵۵-۴۵۶۳, Tehran, Iran
Seyed-Hassan Jafari - School of Chemical Engineering, College of Engineering, University of Tehran, P.O. Box:۱۱۱۵۵-۴۵۶۳, Tehran, Iran
Ghasem Amoabediny - School of Chemical Engineering, College of Engineering, University of Tehran, P.O. Box:۱۱۱۵۵-۴۵۶۳, Tehran, Iran
Mohammad Karimi - Amirkabir University of Technology, Department of Textile Engineering, Hafez Avenue,۱۵۹۱۴ Tehran, Iran

خلاصه مقاله:
i-PP microporous membrane was prepared via thermally induced phase separation (TIPS) method. Diphenyl ether (DPE) was used as a diluent in this report. A microporous structure formed by evaporating the diluent from top of membrane and phase separation was obtained after solidification. The effects of temperature (413, 423 and 433 K) at bottom of samples and evaporation time (1, 3 and 5 min.) on the membrane morphology were investigated by scanning electron microscopy (SEM). SEM micrographs revealed cross sections for membrane prepared to use different evaporation times and temperatures. The difference in diluent concentration on both sides of membrane, forces the diluent to diffuse from inside to the outside of the membrane. Moreover, the amount of evaporated diluent enhances with increasing of evaporation time. The pore size becomes smaller with increasing of temperature at the bottom of the sample. In addition, with increasing of evaporation time, the pore size decreases

کلمات کلیدی:
Thermally induced phase separation, Isotactic polypropylene, Microporous membrane

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/134148/