Four-Component Synthesis of Polyhydroquinolines via Unsymmetrical Hantzsch Reaction Employing Cu-IRMOF-۳ as a Robust Heterogeneous Catalyst
عنوان مقاله: Four-Component Synthesis of Polyhydroquinolines via Unsymmetrical Hantzsch Reaction Employing Cu-IRMOF-۳ as a Robust Heterogeneous Catalyst
شناسه ملی مقاله: JR_CHM-6-9_001
منتشر شده در در سال 1401
شناسه ملی مقاله: JR_CHM-6-9_001
منتشر شده در در سال 1401
مشخصات نویسندگان مقاله:
Reza Taghavi - Organic and Nano Group (ONG), Department of Chemistry, Iran University of Science and Technology (IUST), PO Box ۱۶۸۴۶-۱۳۱۱۴, Tehran, Iran
Sadegh Rostamnia - Organic and Nano Group (ONG), Department of Chemistry, Iran University of Science and Technology (IUST), PO Box ۱۶۸۴۶-۱۳۱۱۴, Tehran, Iran
خلاصه مقاله:
Reza Taghavi - Organic and Nano Group (ONG), Department of Chemistry, Iran University of Science and Technology (IUST), PO Box ۱۶۸۴۶-۱۳۱۱۴, Tehran, Iran
Sadegh Rostamnia - Organic and Nano Group (ONG), Department of Chemistry, Iran University of Science and Technology (IUST), PO Box ۱۶۸۴۶-۱۳۱۱۴, Tehran, Iran
In this report, an IRMOF-۳ was synthesized via a solvothermal method and then used as support for stabilizing Cu(II) ions. Characterization methods such as FT-IR, XRD, SEM, and BET were employed to analyze produced Cu@IRMOF-۳, demonstrating that the suggested catalyst effectively conserved its structure throughout the synthesis processes. The FT-IR results indicate that the presence of the -NH۲ group in the structure of the MOF helped stabilize the Cu(II) ions. The manufactured catalyst was used to prepare polyhydroquinoline derivatives which showed superior results.
کلمات کلیدی: Metal-organic Frameworks, Polyhydroquinoline, IRMOF-۳, Unsymmetrical Hantzsch reaction
صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/1480459/