CIVILICA We Respect the Science
(ناشر تخصصی کنفرانسهای کشور / شماره مجوز انتشارات از وزارت فرهنگ و ارشاد اسلامی: ۸۹۷۱)

Bifunctional Polyethylene Glycol/ethylenediamine Nanomagnetic Phase-Transfer Catalyst: Preparation, Characterization, and Application in Knoevenagel Condensation

عنوان مقاله: Bifunctional Polyethylene Glycol/ethylenediamine Nanomagnetic Phase-Transfer Catalyst: Preparation, Characterization, and Application in Knoevenagel Condensation
شناسه ملی مقاله: JR_CHM-7-6_006
منتشر شده در در سال 1402
مشخصات نویسندگان مقاله:

Fatemeh Hakimi - Department of Chemistry, Payame Noor University (PNU), P.O. Box, ۱۹۳۹۵-۳۶۹۷, Tehran, Iran
Abolfazl Sharifi-Zarchi - Department of Chemistry, Payame Noor University (PNU), P.O. Box, ۱۹۳۹۵-۳۶۹۷, Tehran, Iran
Elham Golrasan - Department of Chemistry, Payame Noor University (PNU), P.O. Box, ۱۹۳۹۵-۳۶۹۷, Tehran, Iran

خلاصه مقاله:
In the present study, an efficient and recyclable heterogeneous phase-transfer catalyst was prepared through the functionalization of magnetic nanoparticles with ethylenediamine and polyethylene glycol. After being characterized by various physico-chemical techniques, the bifunctional magnetic nanocomposite was used as a heterogeneous phase-transfer catalyst in the Knoevenagel condensation of aryl aldehydes with active methylene compounds under mild and green conditions. This procedure has several advantages such as high yield of products, short time of reaction, easy workup, mild reaction conditions, low amount of catalyst, and catalyst recoverability.

کلمات کلیدی:
Knoevenagel Condensation Reusable Catalyst Phase, Transfer Catalyst Bifunctional Nanocomposite Aqueous Media

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/1650701/