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Graphene Oxide Modified with Tetramethylethylenediamine Ammonium Salt as a Powerful Catalyst for Production of Trisubstituted Imidazoles

عنوان مقاله: Graphene Oxide Modified with Tetramethylethylenediamine Ammonium Salt as a Powerful Catalyst for Production of Trisubstituted Imidazoles
شناسه ملی مقاله: JR_AJGC-8-3_004
منتشر شده در در سال 1403
مشخصات نویسندگان مقاله:

Safie Mehrizi Marvast - Department of Chemistry, Payame Noor University, Tehran, Iran
Esmael Rostami - Department of Chemistry, Payame Noor University, Tehran, Iran

خلاصه مقاله:
A new and efficient graphene oxide catalyst was synthesized in this study to prepare trisubstituted imidazoles. Graphene oxide was first modified with ۲-chloroethanol, and then treated with N,N,N,N-tetramethylethylenediamine. After that, the obtained catalyst was characterized by XRD, FTIR, FESEM, EDAX, and TGA. The reported catalyst was utilized for the synthesis of trisubstituted imidazoles from benzil, aldehydes, and ammonium acetate. Reaction efficiently proceeded via a one-pot multicomponent route under solvent-free conditions. Catalyst offered some advantages over reported ones such as sustainability, cost-effectiveness, ease of handling, storage, and recovery, in addition to non-metal structure. The reported procedure has a series of benefits, including medium conditions, high yields, no by-products, short reaction times, and easy work-up. Reported catalyst can be used in chemistry, material sciences, and related disciplines for diverse applications.

کلمات کلیدی:
Graphene oxide ۲, Chloroethanol Ionic Liquid Tetramethylethylenediamine Trisubstituted Imidazole Green chemistry

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/1965367/