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Synthesis and characterization of Ag/Ag2CO3 nanoparticles stabilized over montmorillonite

عنوان مقاله: Synthesis and characterization of Ag/Ag2CO3 nanoparticles stabilized over montmorillonite
شناسه ملی مقاله: TCPCO01_178
منتشر شده در اولین همایش ملی تکنولوژی های نوین در شیمی و پتروشیمی در سال 1393
مشخصات نویسندگان مقاله:

sh Sohrabnezhad - Department of Chemistry, Faculty of Science, University of Guilan, P.O.Box ۱۹۱۴ Rasht. Iran
M.J Mehdipour - Department of Chemistry, Faculty of Science, University of Guilan, P.O.Box ۱۹۱۴ Rasht. Iran
a Sadeghi - Department of Chemistry, Faculty of Science, University of Guilan, P.O.Box ۱۹۱۴ Rasht. Iran

خلاصه مقاله:
The precipitation method was used for synthesis of Ag2Co3 bulk and Ag2CO3-MMT nanocamposite samples in two different solvent, ethylene glycol and water. Thesamples were characterized by diffuse reflectance spectroscopy (DRS), X-ray diffraction (XRD), and transmission electron microscopy (TEM). The mean diameter of Ag and Ag2CO3nanoparticles was evaluated at ~2-3 and ~10-12 nm, respectively. XRD results showed that inethylene glycol solvent all Ag+ ions reduced to metallic silver. But Ag/Ag2CO3-MMT nanocomposite can synthesized in water solvent. X-ray diffraction patterns indicate thatMMT (1.22 nm) has a d-spacing lower than Ag2CO3-MMT nanocomposite (1.86 nm). This result implied that Ag/Ag2CO3 nanoparticles can exist in micropore of MMT. The diffusereflectance spectra show that the value of band gap energy for Ag/Ag2CO3-MMTnanocomposite is (2.56 eV) so nanocatalyst is a good candidate for plasmon photocatalyst applications or antibacterial activity.

کلمات کلیدی:
nanocomposite, montmorillonite, antibacterial

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/244402/