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Affecting parameters on the microstructural morphology of polysulfone membranes via nonsolvent induced phase separation

عنوان مقاله: Affecting parameters on the microstructural morphology of polysulfone membranes via nonsolvent induced phase separation
شناسه ملی مقاله: ICHEC07_206
منتشر شده در هفتمین کنگره ملی مهندسی شیمی در سال 1390
مشخصات نویسندگان مقاله:

Parya Amirabedi - Faculty of Chemical Engineering, Sahand University of Technology, Tabriz, Iran . Membrane Technology Research Center, Sahand University of Technology, Tabriz, Iran
reza Yegani - Faculty of Chemical Engineering, Sahand University of Technology, Tabriz, Iran . Membrane Technology Research Center, Sahand University of Technology, Tabriz, Iran
Hamed Soleymani - Faculty of Chemical Engineering, Sahand University of Technology, Tabriz, Iran . Membrane Technology Research Center, Sahand University of Technology, Tabriz, Iran

خلاصه مقاله:
Flat sheet polysulfone membranes were prepared by phase inversion process. The effect of composition and temperature of coagulation bath and concentration ofpolymer in dope solution on the morphology of membranes were investigated. Changing the bath composition from pure water to the solution with composition of 60/40 (w/w) of NMP and water increased the porosity of top layer and the finger-like macrovoid structure near the support side of the membranes was decreased. The same result observed when coagulation bath temperature increased from 25 °C to 60 °C The morphology of membranes was analyzed by scanning electron microscope and performance of membranes was investigated in terms of pure water permeability and tensile strength. The experimental results show that increasing polymer concentration from 12 to 15 wt%, decreases pure waterpermeability and increases tensile strength. For both polymeric compositions, with increasing of coagulation bath temperature, the tensile strength and pure water permeability of the membranes increased, simultaneously

کلمات کلیدی:
phase inversion, coagulation bath, macrovoid structure, morphology

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/340959/