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Periodic mesoporous organosilica (PMO) or traditional mesoporous silicas? Aspects and scopes in aerobic oxidation

عنوان مقاله: Periodic mesoporous organosilica (PMO) or traditional mesoporous silicas? Aspects and scopes in aerobic oxidation
شناسه ملی مقاله: NZEOLITE02_028
منتشر شده در دومین کنفرانس ملی زئولیت ایران در سال 1394
مشخصات نویسندگان مقاله:

Esmail Doustkhah - Young Researchers and Elite Club, Maragheh Branch, Islamic Azad University, Maragheh, Iran
Sadegh Rostamnia - Organic and Nano Group(ONG), Department of Chemistry, University of Maragheh, P.O. Box ۱۴۱۱۵-۱۷۵, Maragheh, Iran
Bwhzad Zeynizadeh - Department of Chemistry, Faculty of Science, Urmia University, Urmia ۵۷۱۵۹-۱۶۵, Iran

خلاصه مقاله:
In this paper, highly porous periodic mesoporous organosilica (PMO) with ionic liquid nature of pore walls based on imidazolium bridge was synthesized Pd ions were supported on the PMO (Pd@Im-PMO). This was successfully incorporated in the catalysis of two different types of Alcohol oxidation reactions. This catalytic reaction in the presence of Pd@Im-PMO had high product yield. The catalyst was characterized by FTIR, TEM, SEM, EDX, XRD and TGA and. Recyclability of the catalyst was confirmed by reusing it in 10 runs.

کلمات کلیدی:
Pd@Im-PMO; aerobic oxidation; periodic mesoporous organosilica; ionic liquid PMO;

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/397125/