CIVILICA We Respect the Science
(ناشر تخصصی کنفرانسهای کشور / شماره مجوز انتشارات از وزارت فرهنگ و ارشاد اسلامی: ۸۹۷۱)

A DFT study on the mechanism of three-component reaction between Cyclohexyl Isocyanide, dimethyl acetylenedicarboxylate and 2- mercaptobenzoxazole

عنوان مقاله: A DFT study on the mechanism of three-component reaction between Cyclohexyl Isocyanide, dimethyl acetylenedicarboxylate and 2- mercaptobenzoxazole
شناسه ملی مقاله: ISPTC18_045
منتشر شده در هجدهمین همایش شیمی فیزیک ایران در سال 1394
مشخصات نویسندگان مقاله:

M Zakarianezhad - Department of Chemistry, K.N. Toosi University of Technology, Tehran, Iran
B Makiabadi - Department of Chemistry, K.N. Toosi University of Technology, Tehran, Iran
Pouria Sotoudeniakorrani - Department of Chemistry, K.N. Toosi University of Technology, Tehran, Iran
Elham Zeydabadi - Department of Chemistry, K.N. Toosi University of Technology, Tehran, Iran

خلاصه مقاله:
Multicomponent reactions (MCRs), which have more than two reactants in a sequentialfashion to give products that retain the majority of the atoms of the starting materials, canlead to valuable heterocyclic scaffolds in a rapid and highly selective manner, and thus haveattracted more and more attention over the past decades [1-3]. Due to the extraordinaryfunction of isocyanide derivatives, isocyanide-based MCRs are frequently exploited, andsome examplesof the MCRs using isocyanide as a component have been reportedin recentyears [4,5]. We attempt to explore the mechanism of the reaction of cyclohexyl Isocyanideand diamethyl acetylenedicarboxylate with 2-Mercaptobenzoxazole.

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/552504/