κ-Carrageenan as an efficient, green, bifunctional and reusable catalyst for one-pot synthesis of Hantzsch 1,4-dihydropyridine
عنوان مقاله: κ-Carrageenan as an efficient, green, bifunctional and reusable catalyst for one-pot synthesis of Hantzsch 1,4-dihydropyridine
شناسه ملی مقاله: IRANCC20_771
منتشر شده در بیستمین کنگره شیمی ایران در سال 1397
شناسه ملی مقاله: IRANCC20_771
منتشر شده در بیستمین کنگره شیمی ایران در سال 1397
مشخصات نویسندگان مقاله:
Nahid Musivand - Department of Chemistry, Iran University of Science & Technology, Tehran ۱۶۸۴۶۱۳۱۱۴, Iran
Mohammad G. Dekamin - Department of Chemistry, Iran University of Science & Technology, Tehran ۱۶۸۴۶۱۳۱۱۴, Iran
Ghasem Rezanejade Bardajee - Department of Chemistry, Payame Noor University, P.O. BOX, ۱۹۳۹۵-۳۶۹۷, Tehran, Iran
خلاصه مقاله:
Nahid Musivand - Department of Chemistry, Iran University of Science & Technology, Tehran ۱۶۸۴۶۱۳۱۱۴, Iran
Mohammad G. Dekamin - Department of Chemistry, Iran University of Science & Technology, Tehran ۱۶۸۴۶۱۳۱۱۴, Iran
Ghasem Rezanejade Bardajee - Department of Chemistry, Payame Noor University, P.O. BOX, ۱۹۳۹۵-۳۶۹۷, Tehran, Iran
Developing chemical processes using more environmentally acceptable catalysts, chemicals and atom efficient procedures have been emerged as subjects of innovation in green chemistry. For instance, the terrible impact of non-biodegradable wastes is still an open challenge in either developed or developing countries. In this regard, great efforts have been performed to use different bio-based feedstocks such as chitosan, chitin, starch, cellulose, gelatin, wool and alginates as biopolymeric support in the transition metal-based heterogeneous catalytic systems. On the other hand, multicomponent reactions have been recognized as a vast improvement for synthetic chemists. Multicomponent reactions are the reactions with three or more substratets, which lead to the production of complex molecules, especially heterocyclic complex products.1-3 Carrageenan is a natural carbohydrate (polysaccharide) obtained from edible red seaweeds. Carrageenans are used in a variety of commercial applications as gelling, thickening, and stabilising agents, especially in food products and sauces. Carrageenans are also used in pharmaceutical, drug delivery, cosmetics, experimental medicine and textile industries.4Kappa-Carrageenan was found to be an efficient, bifunctional, recyclable, economical, environment-friendly and green catalyst for the one-pot multicomponent synthesis of 1,4-dihydropyridines (1,4-DHPs) via the Hantzsch reaction. The mild reaction conditions, short reaction times, good yields and the nontoxic catalyst make this method especially attractive.5, 6
صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/851394/