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Synthesis and Characterization of Copper (II) Coordination Polymer with 1,3,5-Benzenetricarboxylic Acid Ligand

عنوان مقاله: Synthesis and Characterization of Copper (II) Coordination Polymer with 1,3,5-Benzenetricarboxylic Acid Ligand
شناسه ملی مقاله: IICC20_080
منتشر شده در بیستمین سمینار شیمی معدنی ایران در سال 1397
مشخصات نویسندگان مقاله:

Mohamad Darodi pur - Department of Chemistry, University of Sistan and Baluchestan, P.O. Box ۹۸۱۳۵-۶۷۴, Zahedan, Iran
Ali Reza Rezvani - Department of Chemistry, University of Sistan and Baluchestan, P.O. Box ۹۸۱۳۵-۶۷۴, Zahedan, Iran
Sania Saheli - Department of Chemistry, University of Sistan and Baluchestan, P.O. Box ۹۸۱۳۵-۶۷۴, Zahedan, Iran

خلاصه مقاله:
In recent years, metal-organic frameworks (MOFs) or coordination polymers (CPs) have attracted attention due to their potential applications for gas storage, catalysis, molecular magnetism and sensors. The combinations of metal ions and organic ligands are designed in the form of one-dimensional (1D), two-dimensional (2D) and three-dimensional (3D) frameworks. The coordination geometry of the metal ions and the organic ligand geometry affect the structure and topology of the MOFs. In this research, a novel metal-organic framework (MOF) formulated as, [Cu2(Hbtc)2(H2O)6] (1), has been synthesized with reaction between copper (II) and 1,3,5-benzenetricarboxylic acid. The product has been characterized by IR spectroscopy and X-ray diffraction. The complex (1) is crystallized in the monoclinic crystal system with P21/n space group. Crystal data for complex (1): a= 6.7575(3), b= 18.8415(6), c= 8.5187(5)[Å], ? = 92.366(4)[°], Z= 2.

کلمات کلیدی:
Coordination polymer, Metal-Organic framework, Copper complex, 1,3,5-benzenetricarboxylic acid

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/876381/