The Effect of Synthetic Procedures on Formation of Two Silver Coordination Polymers and their Antibacterial Activities
محل انتشار: فصلنامه شیمی معدنی، دوره: 5، شماره: 1
سال انتشار: 1400
نوع سند: مقاله ژورنالی
زبان: انگلیسی
مشاهده: 230
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شناسه ملی سند علمی:
JR_ICR-5-1_005
تاریخ نمایه سازی: 9 اردیبهشت 1400
چکیده مقاله:
The effect of synthesis procedure on formation of [Ag۲(μ۲-py-۴-c)۲]n (۱) and {[Ag(py-۴-c)(Hpy-۴-c)]۱/۲.[Ag(py-۴-c)]}n (۲) coordination polymers (py-۴-c = pyridine-۴-carboxylate) were studied. Pyridine-۴-carboxylic acid (Hpy-۴-c) was deprotonated by KOH and the anionic ligand was become available for interaction with the metal ion. AgNO۳ was added to the ligand solution with two different rates in two conditions of bulk and ultrasonic bath which yielded to [Ag۲(μ۲-py-۴-c)۲]n (۱) on stirrer and a different coordination polymer in ultrasonic bath, {[Ag(py-۴-c)(Hpy-۴-c)]۱/۲.[Ag(py-۴-c)]}n (۲). Formation of [Ag۲(μ۲-py-۴-c)۲]n (۱) and {[Ag(py-۴-c)(Hpy-۴-c)]۱/۲.[Ag(py-۴-c)]}n (۲) were investigated with different analyses such as Powder X-ray Diffraction (PXRD), Fourier-Transform Infrared spectroscopy (FT-IR), Scanning Electron Microscopy (SEM) and Thermogravimetric analysis (TGA). Moreover, antibacterial activity of the samples was investigated against both gram-negative (E. coli) and gram-positive (S. aureus) bacteria’s.
کلیدواژه ها:
نویسندگان
Mahnoosh Zamani Isfahani
School of Chemistry, College of Science, University of Tehran, Tehran, Iran
Kamran Akhbari
School of Chemistry, College of Science, University of Tehran, Tehran, Iran
Anukorn Phuruangrat
Department of Materials Science and Technology, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla, Thailand