Investigation on polysulfone blended NH۲-MIL۱۲۵ (Ti) membrane for photocatalytic degradation of Methylene Blue dye

سال انتشار: 1399
نوع سند: مقاله ژورنالی
زبان: انگلیسی
مشاهده: 228

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شناسه ملی سند علمی:

JR_JWENT-5-3_004

تاریخ نمایه سازی: 25 اردیبهشت 1400

چکیده مقاله:

< p>Membrane hybrid processes represent innovative separation technologies in which each technique complements the advantages and overcomes the challenges of the other. Dye removal from wastewater is an application for which membrane hybrid processes are widely applied. The focus of this study is also on development of a membrane hybrid process for dye removal from wastewater. Different proportions of NH۲-MIL۱۲۵(Ti) were embedded in a PSf polymeric membrane through the phase inversion method and the membrane performance was evaluated for the degradation of a Methylene Blue dye under three different light conditions of dark environment, UV and visible light irradiation. The synthesized membranes were characterized by FTIR, XRD, and FE-SEM measurements. NH۲-MIL۱۲۵(Ti) nanoparticles were successfully entrapped in the PSf membrane through a simple phase inversion method and addition of NH۲-MIL۱۲۵(Ti) to the PSf membrane resulted in the improvement of membrane porosity. Up to ۶۰% of dye degradation was observed with the ۱% NH۲-MIL۱۲۵(Ti)/PSf nanocomposite membrane after ۳۰۰ minutes of UV light irradiation. Degradation kinetics followed a pseudo first order model, evidence of possible changes in the membrane properties upon irradiation with simulated solar radiation.

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نویسندگان

Abbas Ahmadi

UNESCO Chair on Water Reuse (UCWR), School of Chemical Engineering, College of Engineering, University of Tehran, Tehran, Iran

Mohammad Hossein Sarrafzadeh

UNESCO Chair on Water Reuse (UCWR), School of Chemical Engineering, College of Engineering, University of Tehran, Tehran, Iran

Maryam Mohamadi

UNESCO Chair on Water Reuse (UCWR), school of chemical engineering, college of engineering, University of Tehran, Tehran, Iran

Zeinab Mahdigholian

UNESCO Chair on Water Reuse (UCWR), School of Chemical Engineering, College of Engineering, University of Tehran, Tehran, Iran

Akram Hosseinian

Department of Engineering Science, College of Engineering, University of Tehran, P.O. Box ۱۱۳۶۵-۴۵۶۳, Tehran, Iran

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