Basic dyes removal by adsorption process using magnetic Fucus vesiculosus (brown algae)

سال انتشار: 1399
نوع سند: مقاله ژورنالی
زبان: انگلیسی
مشاهده: 238

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شناسه ملی سند علمی:

JR_JWENT-5-3_006

تاریخ نمایه سازی: 25 اردیبهشت 1400

چکیده مقاله:

Abstract: In this project, new magnetic Fucus vesiculosus (m-FV) nanoparticles with a high adsorption capacity of cationic dyes were prepared. To reach a nanocomposite with effective performance, Fucus vesiculosus (FV) was modified using ultrasound. Then, the Fe۲+/Fe۳+ ions were co-precipitated in situ to induce magnetic feature to FV particles. Solutions contaminated with the model cationic dyes, methylene blue (MB) and crystal violet (CV), were treated by employing m-FV particles. Study on time of dyes removal showed a fast removing rate of MB and CV, reaching equilibrium at ۱۰ and ۵ minutes, respectively. Analysis of experimental kinetic data by the pseudo-first-order and pseudo-second-order models indicated a well-describing of data by the pseudo-second-order model. The isotherm data of adsorption of both cationic dyes on m-FV were modeled and revealed a well-describing with the Langmuir model. According to the Langmuir model, maximum adsorption capacities of ۵۷۷ mg/g for MB and ۱۰۶۲ mg/g for CV on m-FV observed. Easy recovery, good recyclability, pH-independent property, as well as the high capability in the removal of cationic dyes, the m-FV can be considered an effective and eco-friendly bioadsorbent in the treatment of dye contaminated solutions.

نویسندگان

Hessam Jafari

Polymer Research Laboratory, Department of Chemistry, Faculty of Science, University of Maragheh, ۵۵۱۸۱-۸۳۱۱۱, Maragheh, Iran.

Gholam Reza Mahdavinia

Polymer Research Laboratory, Department of Chemistry, Faculty of Science, University of Maragheh, ۵۵۱۸۱-۸۳۱۱۱, Maragheh, Iran.

Bagher Kazemi

Department of Chemistry, Iran University of Science and Technology, Tehran ۱۶۸۴۶-۱۳۱۱۴, Iran.

Shahrzad Javanshir

Department of Chemistry, Iran University of Science and Technology, Tehran ۱۶۸۴۶-۱۳۱۱۴, Iran.

Samira Alinavaz

Polymer Research Laboratory, Department of Chemistry, Faculty of Science, University of Maragheh, ۵۵۱۸۱-۸۳۱۱۱, Maragheh, Iran.

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