Ultrasonic-assisted synthesis and structural characterization of novel Cd(II) nano coordination polymer
سال انتشار: 1400
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 289
- صدور گواهی نمایه سازی
- من نویسنده این مقاله هستم
استخراج به نرم افزارهای پژوهشی:
شناسه ملی سند علمی:
ICNNA02_109
تاریخ نمایه سازی: 4 مهر 1400
چکیده مقاله:
A new Cd(II) nano coordination polymer, {[Cd(DADMBTZ)۲(NO۲)۲]}n (۱), has been synthesized and characterized by IR, ۱H, ۱۳C, ۱۱۳Cd NMR spectroscopy, elemental analysis and single crystal X-ray determination. The coordination number of cadmium atom in complex is six with coordinated environments of distorted octahedral, CdN۴O۲. In reaction with DADMBTZ, the ligand DADMBTZ acts as bidentate in complex to form five-membered chelate rings with different internal angles in coordination polyhedron. Two mono dentate nitroto ions occupy the equatorial position. As-prepared Cd(II) nano coordination polymer was characterized by X-ray diffraction measurements (XRD), scanning electron microscopy (SEM).
کلیدواژه ها:
نویسندگان
Akram Hosseinian
School of Engineering Science, College of Engineering, University of Tehran, P.O.Box ۱۱۳۶۵-۴۵۶۳, Tehran, Iran