Shape Selective Pillared Clay Catalysts for P-Xylene Production
محل انتشار: فصلنامه مواد پیشرفته و فرآوری، دوره: 3، شماره: 3
سال انتشار: 1394
نوع سند: مقاله ژورنالی
زبان: انگلیسی
مشاهده: 149
فایل این مقاله در 11 صفحه با فرمت PDF قابل دریافت می باشد
- صدور گواهی نمایه سازی
- من نویسنده این مقاله هستم
استخراج به نرم افزارهای پژوهشی:
شناسه ملی سند علمی:
JR_JMATPR-3-3_004
تاریخ نمایه سازی: 13 مهر 1400
چکیده مقاله:
Shape selective xylene production is very important in the polymer industry because of its extensive use as raw material for monomer preparation. The acidity associated with the Lewis and Broensted centers present in the pillars interlayered clay and its textural properties allows good catalytic activity and shape selectivity toward p-xylene production. So, in the present study, ultrasonic and microwave as a new and efficient method was used in the preparation of Co, Cr and ZrO۲-pillared clay with enhanced textural properties, improved thermal stability and significant reduction in processing time. Catalytic alkylation of toluene with methanol was carried out over the prepared catalysts in a catalytic flow system operated under atmospheric pressure at a temperature range ۲۵۰-۴۵۰oC. Results indicated that the pillaring of montmorilonitic clay material with polyoxy-metalic cations (Zr-, Cr- and Co-) improves the texture properties and thermal stability of the obtained catalysts. The Co-PILC catalyst is the most active and selective catalyst towards p-xylene formation, i.e. Co-PILC catalyst is a shape selective for p-xylene formation.
کلیدواژه ها:
نویسندگان
dalia radwan
egyptian petroleum research institute, Nasser City, Cairo, Egypt
Mohamed Ebiad
Egyptian petroleum research institute, Nasser city, Cairo, Egypt
Sara Mekhail
Egyptian petroleum research institute, Nasser city, Cairo, Egypt