Synthesis and characterization of a dioxomolybdenum(VI) aminohydrazone complex and its performance as an efficient homogeneous catalyst in the selective oxidation of benzylic alcohols
محل انتشار: فصلنامه شیمی معدنی، دوره: 5، شماره: 2
سال انتشار: 1400
نوع سند: مقاله ژورنالی
زبان: انگلیسی
مشاهده: 191
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شناسه ملی سند علمی:
JR_ICR-5-2_004
تاریخ نمایه سازی: 12 دی 1400
چکیده مقاله:
A dioxomolybdenum(VI) complex was successfully synthesized by the reaction between [MoO۲(acac)۲] and a tridentate ligand obtained from the condensation of ۴-aminobenzohydrazide and ۳-ethoxysalicylaldehyde. The structures of synthesized products were explored through elemental analysis (CHN) and various spectroscopic techniques such as FT-IR, ۱H NMR, and ۱۳C NMR. Moreover, the complex was utilized in the selective oxidizing of benzylic alcohols to the corresponding aryl aldehydes by the use of urea hydrogen peroxide (UHP) in acetonitrile under reflux conditions. The present protocol has several advantages, including short reaction times, high product yields, and simplicity in operation.
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نویسندگان
Hadi Kargar
Department of Chemical Engineering, Faculty of Engineering, Ardakan University, P.O. Box ۱۸۴, Ardakan, Iran
Mehdi Fallah-Mehrjardi
Department of Chemistry, Payame Noor University, ۱۹۳۹۵-۳۶۹۷, Tehran, Iran