Fabrication of dye-sensitized solar cells based on the electrospun TiO۲nanofibres sensitized by the cocktail of natural dyes
سال انتشار: 1401
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 217
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شناسه ملی سند علمی:
IAAMM02_066
تاریخ نمایه سازی: 17 مرداد 1401
چکیده مقاله:
Here, we demonstrated that outstanding electrical and morphological characteristics of TiO۲ nanofibressensitized by the cocktail of natural dyes can effectively improve and stabilize the dye-sensitized solarcells (DSSCs). The TiO۲ nanofibres were fabricated using a cost-effective and applicable electrospinningtechnique. The FESEM results demonstrated that the continuous bead-free nanofibres were successfullyfabricated, which indicates good control of the electrospinning conditions. Based on the BET results, thetransformation of nanoparticles to nanofibres increased the BET surface area and pore size. Then, a facileone-step approach was employed to fabricate TiO۲ nanofibres-based DSSCs that produced a highly porousnetwork of TiO۲ without the nanofibre layer undergoing multiple cracks upon calcination. Based on thephotovoltaic results, the DSSCs fabricated by the electrospun TiO۲ nanofibres showed the highest 𝐼𝑠𝑐 , 𝑉𝑜𝑐 ,and 𝜂 of ۱.۸۰ mA, ۰.۴۰ V, and ۱.۲۴%, respectively. This is because that the one-dimensional morphologyof electrospun nanofibres provides better charge conduction due to the combined effect of the reducedgrain boundaries and a higher specific surface area. The results also showed that the DSSC based on theTiO۲ nanofibres retained about ۶۳% of its initial efficiency after ۱۴ days, while DSSCs based on the TiO۲nanoparticles maintained about ۲۷%, respectively.
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نویسندگان
Malihe Golshan
Department of Chemical Engineering, Faculty of Petroleum, Gas, and Petrochemical Engineering, PersianGulf University, Bushehr, ۷۵۱۶۹, Iran.
Shahriar Osfouri
Department of Chemical Engineering, Faculty of Petroleum, Gas, and Petrochemical Engineering, PersianGulf University, Bushehr, ۷۵۱۶۹, Iran.
Reza azin
Department of Petroleum Engineering, Faculty of Petroleum, Gas, and Petrochemical Engineering, PersianGulf University, Bushehr, ۷۵۱۶۹, Iran.
tahmineh jalali
Department of Physics, Faculty of Science, Persian Gulf University, Bushehr, ۷۵۱۶۹, Iran.
navid r Moheimani
Algae R&D Centre, Environmental and Conservation Sciences, Murdoch University, Murdoch, ۶۱۵۰,Western Australia.