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مقالات فارسیISIکنفرانسهاژورنالها

An Environmentally Friendly Method for Recovery of Metals from Cathode Material of Lithium-Ion Batteries using L-Glutamic, Malonic, and Ascorbic acid

محل انتشار: مجله معدن و محیط زیست، دوره: 13، شماره: 4
سال انتشار: 1401
نوع سند: مقاله ژورنالی
زبان: انگلیسی
مشاهده: 151

فایل این مقاله در 18 صفحه با فرمت PDF قابل دریافت می باشد

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لینک ثابت به این مقاله:
https://civilica.com/doc/1597034

شناسه ملی سند علمی:

JR_JMAE-13-4_016

تاریخ نمایه سازی: 12 بهمن 1401

چکیده مقاله:

In this research work, with a simple, safe, and environmentally friendly approach to hydrometallurgy, a method for the recovery of lithium (Li), cobalt (Co), and nickel (Ni) from LIBs is suggested. The cathode materials are leached by malonic acid, as the leaching agent, and ascorbic acid, as the reducing agent in the first process, and by L-glutamic acid, as the leaching agent, and ascorbic acid, as the reducing agent in the second process. In order to optimize the leaching parameters including temperature, organic acid concentration, ascorbic acid concentration, type of organic acid, pulp density, and time, response surface methodology (RSM) of the experimental design process is used. According to the results, compared to L-glutamic acid in the second process, the leaching recovery increase considerably with malonic acid in the first process. This normally occurs due to the higher solubility of malonic acid in water, which results in a better complexation and a higher chelation rate. By contrast, as solubility of L-glutamic acid in water is low, metal-acid surface reaction and poor complexation are unavoidable. According to the statistical analysis of the results and validation testing, optimal experimental leaching occurs at the reaction temperature of ۸۸ °C, organic acid concentration of ۰.۲۵ M, ascorbic acid concentration of ۰.۰۳ M, pulp density of ۱۰ g/L, and leaching time of ۲ h, via which metal recovery of ۱۰۰% Li, ۸۱% Co, and ۹۹% Ni is achieved. Before and after acidic leaching, the sample active materials are qualitatively and quantitatively analyzed using X-ray diffraction, X-ray fluorescence, particle size analyzer, scanning electron microscope, energy dispersive spectroscopy, and atomic absorption spectroscopy.

کلیدواژه ها:

Lithium-Ion Battery Recovery ، L-Glutamic Acid ، Malonic Acid ، Leaching Optimization

نویسندگان

Laleh Sohbatzadeh

School of Mining Engineering, Faculty of Engineering, University of Tehran, Tehran, Iran

Sied Ziaedin Shafaei Tonkaboni

School of Mining Engineering, Faculty of Engineering, University of Tehran, Tehran, Iran

Mohammad Noaparast

School of Mining Engineering, Faculty of Engineering, University of Tehran, Tehran, Iran

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  • . He, L.P., Sun, S.Y., and Yu, J.G. (۲۰۱۸). Performance ...
  • . Nayaka, G., Zhang, Y., Dong, P., Wang, D., Pai, ...
  • . Meshram, P., Pandey, B.D., Mankhand, T.R., and Deveci, H. ...
  • . Li, L., Dunn, J.B., Zhang, X.X., Gaines, L., Chen, ...
  • . Tang, X., Tang, W., Duan, J., Yang, W., Wang, ...
  • . Xiao, J., Niu, B., Song, Q., Zhan, L., and ...
  • . Gao, W., Liu, C., Cao, H., Zheng, X., Lin, ...
  • . Liu, F., Peng, C., Ma, Q., Wang, J., Zhou, ...
  • . Chen, X., Guo, C., Ma, H., Li, J., Zhou, ...
  • . Billy, E., Joulié, M., Laucournet, R., Boulineau, A., De ...
  • . Sommerville, R., Zhu, P., Rajaeifar, M. A., Heidrich, O., ...
  • . Li, J., He, Y., Fu, Y., Xie, W., Feng, ...
  • . Meng, F., Liu, Q., Kim, R., Wang, J., Liu, ...
  • . Zhang, X., Bian, Y., Xu, S., Fan, E., Xue, ...
  • . Zheng, Y., Song, W., Mo, W.t., Zhou, L., and ...
  • . Wang, C., Wang, S., Yan, F., Zhang, Z., Shen, ...
  • . Tang, Y., Zhang, B., Xie, H., Qu, X., Xing, ...
  • . Zhang, X., Li, L., Fan, E., Xue, Q., Bian, ...
  • . Guo, Y., Li, F., Zhu, H., Li, G., Huang, ...
  • . He, L.P., Sun, S.Y., Song, X.F., and Yu, J.G. ...
  • . Chen, X., Ma, H., Luo, C., and Zhou, T. ...
  • . Lee, C.K., and Rhee, K.I. (۲۰۰۳). Reductive leaching of ...
  • . Yao, L., Feng, Y., and Xi, G. (۲۰۱۵). A ...
  • . Nayaka, G., Pai, K., Santhosh, G., and Manjanna, J. ...
  • . Roshanfar, M., Golmohammadzadeh, R., and Rashchi, F. (۲۰۱۹). An ...
  • . Li, L., Ge, J., Chen, R., Wu, F., Chen, ...
  • . Chen, X., Luo, C., Zhang, J., Kong, J., and ...
  • . Li, L., Fan, E., Guan, Y., Zhang, X., Xue, ...
  • . Gao, W., Zhang, X., Zheng, X., Lin, X., Cao, ...
  • . He, L.P., Sun, S.Y., Mu, Y.Y., Song, X.F., and ...
  • . Li, L., Qu, W., Zhang, X., Lu, J., Chen, ...
  • . Meshram, P., Pandey, B., and Mankhand, T. (۲۰۱۵). Hydrometallurgical ...
  • . Sung, M.H., Park, C., Kim, C.J., Poo, H., Soda, ...
  • . Fu, Y., He, Y., Li, J., Qu, L., Yang, ...
  • . Ku, H., Jung, Y., Jo, M., Park, S., Kim, ...
  • . Zhu, B., Zhang, Y., Zou, Y., Yang, Z., Zhang, ...
  • . Dutta, D., Kumari, A., Panda, R., Jha, S., Gupta, ...
  • . Zhou, S., Zhang, Y., Meng, Q., Dong, P., Fei, ...
  • . Weissman, S.A., and Anderson, N.G. (۲۰۱۵). Design of experiments ...
  • . Yang, Y., Huang, G., Xu, S., He, Y., and ...
  • . Kettler, R.M., Wesolowski, D.J., and Palmer, D.A. (۱۹۹۲). Dissociation ...
  • . Hamborg, E.S., Niederer, J.P., and Versteeg, G.F. (۲۰۰۷). Dissociation ...
  • . Chen, W.S., and Ho, H.J. (۲۰۱۸). Recovery of valuable ...
  • . Golmohammadzadeh, R., Faraji, F., and Rashchi, F. (۲۰۱۸). Recovery ...
  • . Aboyeji, O., Oloke, J., Arinkoola, A., Oke, M., and ...
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