Treatment of mercury(II) with dimethylpyridine-۲,۶-dicarboxylate ligand supported by structural and spectral studies
محل انتشار: ششمین کنفرانس ملی شیمی و توسعه فناوری نانو
سال انتشار: 1401
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 99
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شناسه ملی سند علمی:
NANOTEC06_016
تاریخ نمایه سازی: 21 خرداد 1402
چکیده مقاله:
In this work, a new complex of mercury with dimethylpyridine-۲,۶-dicarboxylate (MPC), was prepared by identified by elemental analysis, FT-IR spectroscopy and single-crystal X-Ray diffraction. The X-ray analysis results revealed that the MPC ligand, after reactions with the KSCN and HgCl۲, gives structures [Hg(MPC)(SCN)Cl]. In the crystal structure of this complex mercury atom has an HgClNO۲S environment with monoclinic pyramidal geometry. In this complex the coordination number of the mercury (II) ion is ۵. The ligand is potentially five dentate but only uses three states. When MPC ligand coordinated to mercury, forms two five membered chilate rings. In the crystal network of the complex there are intermolecular C–H···Cl, C–H···N and C–H···O hydrogen bonds, extending the crystal network into three dimensional
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نویسندگان
Zahra Mardani
Inorganic Chemistry Department, Faculty of ChemistryUrmia University, ۵۷۵۶۱-۵۱۸۱۸Urmia,Iran
Golzar salek
Inorganic Chemistry Department, Faculty of ChemistryUrmia University, ۵۷۵۶۱-۵۱۸۱۸Urmia, Iran