Recent advances on defluorinative carboxylation and decarboxylative fluorination of arenes
محل انتشار: مقالات مروری و پژوهشی شیمی، دوره: 6، شماره: 3
سال انتشار: 1402
نوع سند: مقاله ژورنالی
زبان: انگلیسی
مشاهده: 74
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شناسه ملی سند علمی:
JR_CHRL-6-3_001
تاریخ نمایه سازی: 5 آذر 1402
چکیده مقاله:
Abstract: Compared with most studies in the field of CO۲ utilization, which focused on the carboxylation of C-I, C−Br, C−Cl, C−B, C-Si, C-O bonds, the direct defluorinative carboxylation of C−F bonds is more challenging due to the much higher bond dissociation energy and less reactivity of C−F bonds, for which it is difficult to initiate the oxidative addition process under mild conditions. Recently, various catalytic systems have been developed that allow the direct carboxylation of inert C-F bonds with atmospheric CO۲ and provide versatile methodologies for green synthesis of carboxylic acid derivatives. This review focuses on recent advances in this challenging and hot research topic with special emphasis on the mechanistic details of the reaction pathways.
کلیدواژه ها:
نویسندگان
Hayder Tariq
Department of Pharmacy, Al-Zahrawi University College, Karbala, Iraq
Tala Qassem
Department of Medical Laboratory Technics, Al-Noor University College, Nineveh, Iraq
Hala Bashir
Medical Technical College, Al-Farahidi University, Iraq
Farnaz Behmagham
Department of Chemistry, Miandoab Branch, Islamic Azad University, Miandoab, Iran
Farinaz Shahimi
Department of Chemistry, Payame Noor University, P.O. Box ۱۹۳۹۵-۳۶۹۷ Tehran, Iran