Impact of bridging oxygens formation on optical properties of Fe۳+ doped Li۲O–Al۲O۳–SiO۲–TiO۲ glasses
محل انتشار: فصلنامه سنتز و تفجوشی، دوره: 2، شماره: 1
سال انتشار: 1401
نوع سند: مقاله ژورنالی
زبان: انگلیسی
مشاهده: 62
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شناسه ملی سند علمی:
JR_SYNSINT-2-1_003
تاریخ نمایه سازی: 14 آذر 1402
چکیده مقاله:
In this study, the structural chemistry of Fe۳+ doped Li۲O–Al۲O۳–SiO۲–TiO۲ (LAST) glasses has been analyzed utilizing UV-Vis spectroscopy. Optical parameters like absorption and extinction coefficients, indirect and direct optical band gaps, Urbach energy as well as Fermi energy level of samples were estimated via their absorption spectra. Then, it was tried to make a relationship between the variation of mentioned parameters and structural chemistry of different doped samples. Results of the investigation illustrated that even a little change in the microstructure of glassy samples has an effect on optical parameters and accordingly it could be sensible. Furthermore, it was revealed that Fe۳+ ions have the role of network forming in the structure of glass by increasing the formation of bridging oxygens (BOs) in the matrix.
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نویسندگان
A Faeghinia
Ceramic Department, Materials and Energy Research Center (MERC), P.O. Box ۳۱۷۷۹-۸۳۶۳۴, Karaj, Iran