Studying the Electrochemical Behavior of ۲-amino-۴-methylphenol in the Presence of Penicillin Amine Using Cyclic Voltammetry Technique

سال انتشار: 1396
نوع سند: مقاله ژورنالی
زبان: انگلیسی
مشاهده: 37

فایل این مقاله در 6 صفحه با فرمت PDF قابل دریافت می باشد

استخراج به نرم افزارهای پژوهشی:

لینک ثابت به این مقاله:

شناسه ملی سند علمی:

JR_JPEM-5-1_001

تاریخ نمایه سازی: 24 بهمن 1402

چکیده مقاله:

The studies performed about electrochemical oxidation ۲-amino-۴-methylphenol indicate that ortho-quinone yielded through oxidation of this chemical compound was unstable and it could be used as Michael acceptor under solvent influences, carrier electrolyte, additives and could be transformed into the various compounds in the form of ۱-۴ addition Michael reaction. Based on this, in the paper firstly electrochemical oxidation of ۲-amino-۴-methylphenol in the water has been studied. Then the electrochemical behavior of the compound has been assessed in the presence of nucleophile Penicillin amine under different conditions. The studies indicate that the above compounds could be transformed to new derivatives in the presence of Penicillin amine and phosphate buffer with concentration of ۰.۲ M and pH=۷ during the EC mechanism. Using electrochemical data obtained by performing studies, electrolysis of ۲-amino-۴-methylphenol has been made in the presence of Penicillin amine, which is served as nucleophile and the product has been yielded with suitable practical efficiency. In all cases in order to optimize the electrolysis conditions and to determine the mechanism, cyclic voltammetry (CV) and Controlled Potential Coulometer (CPC) were utilized.

نویسندگان

Davood Kaviani

Young Researchers and Elite Club, East Tehran Branch, Islamic Azad University, Tehran, Iran

Majid Saghi

Department of chemistry, Faculty of science, Arak branch, Islamic Azad University, Arak, Iran

Maryam Agha Mohammadi

Department of chemistry, Faculty of science, Arak branch, Islamic Azad University, Arak, Iran

Mohammad Hosein Bigtan

Department of chemistry, Faculty of science, Arak branch, Islamic Azad University, Arak, Iran

مراجع و منابع این مقاله:

لیست زیر مراجع و منابع استفاده شده در این مقاله را نمایش می دهد. این مراجع به صورت کاملا ماشینی و بر اساس هوش مصنوعی استخراج شده اند و لذا ممکن است دارای اشکالاتی باشند که به مرور زمان دقت استخراج این محتوا افزایش می یابد. مراجعی که مقالات مربوط به آنها در سیویلیکا نمایه شده و پیدا شده اند، به خود مقاله لینک شده اند :
  • H. Yin, Q. Ma, Y. Zhou, S. Ai, L. Zhu, ...
  • A. Rahat, M. R. Nateghi, Electrochemical Impedance Spectroscopy Of Poly(۲-Amino-۴-methylphenol) ...
  • J. Peisach , W. E. Blumberg, A mechanism for the ...
  • J.K. Aronson, Meyler’s side effects of analgesics and anti-inflammatory drugs. ...
  • C. W. Parker, J. Shapiro, M. Kern, H.Eisen, N. Hypersensitivity ...
  • Allen J. Bard, L. R. Faulkner, Electrochemical Methods Fundamentals and ...
  • R. S. Nicholson, I. Shain, Theory of Stationary Electrode Polarography. ...
  • J, Heinze, Cyclic Voltammetry-Electrochemical Spectroscopy, New Analytical Methods(۲۵), Angewandte Chemie ...
  • T.Nomura, G. Nakagawa, Tensammetric determination of microgram amounts of EDTA ...
  • [۱۱[A. Bolognese, R.Liberatore, W. Schäfer, Oxidation of ۲-amino-۴-methylphenol in acidic ...
  • نمایش کامل مراجع