Electrochemical and Quantum Chemical Calculations of Two SchiffBases as Inhibitor for Mild Steel Corrosion inHydrochloric Acid Solution
محل انتشار: دوفصلنامه ایرانی شیمی تجزیه، دوره: 2، شماره: 1
سال انتشار: 1394
نوع سند: مقاله ژورنالی
زبان: انگلیسی
مشاهده: 375
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شناسه ملی سند علمی:
JR_IJAC-2-1_004
تاریخ نمایه سازی: 6 شهریور 1396
چکیده مقاله:
The corrosion inhibition characteristics of two synthesized Schiff bases, namely N, N´-bis(2-hydroxy-6-nitrobenzaldehyde) benzidineand N, N´-bis(salysylaldehyde) benzidine, on the mild steel corrosion in 2.0 M hydrochloric acid have been investigated by weightloss, potentiodynamic polarization and electrochemical impedance spectroscopy techniques. These studies were carried out atdifferent concentrations, temperatures and durations. Polarization measurements indicate that the two inhibitors act as mixed typeinhibitors. The adsorption of inhibitors obeys the Langmuir adsorption isotherm and the thermodynamic parameters (Ea, Kads, ΔG0ads)were calculated and discussed. Quantum chemical calculations were performed to provide further insight into the inhibitionefficiencies determined experimentally.
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نویسندگان
Nasrin Soltani
Department of Chemistry, Payame Noor University, P.O. Box ۱۹۳۹۵-۴۶۹۷, Tehran, I.R. Iran
Hosein Salavati,
Department of Chemistry, Payame Noor University, P.O. Box ۱۹۳۹۵-۴۶۹۷, Tehran, I.R. Iran
Nahid Rasouli,
Department of Chemistry, Payame Noor University, P.O. Box ۱۹۳۹۵-۴۶۹۷, Tehran, I.R. Iran
Mehrnoosh Paziresh,
Department of Chemistry, Payame Noor University, P.O. Box ۱۹۳۹۵-۴۶۹۷, Tehran, I.R. Iran