Electrocatalytic activities of Cu(II)Schiff base complexes encapsulated in nanocavities of zeolite-Y towards a new method for olefins oxidation

سال انتشار: 1396
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 378

فایل این مقاله در 5 صفحه با فرمت PDF قابل دریافت می باشد

استخراج به نرم افزارهای پژوهشی:

لینک ثابت به این مقاله:

شناسه ملی سند علمی:

NZEOLITE04_091

تاریخ نمایه سازی: 11 شهریور 1397

چکیده مقاله:

Metal transition complexes of Schiff base were considered among the other metal complexes due to their potential application in catalytic systems [1-4]. In addition, electrocatalytic performance of transition metal complexes have been becomes a popular research topic in the oxidation process. The work reported herein presents a modified procedure in electrocatalytic oxidation of olefins by CuL1-Y and CuL2-Y as heterogeneous catalysts. However, no such studies are reported for the oxidation of chemical substrates. The results showed that the Schiff base complexes encapsulated in zeolite convert olefins into the corresponding epoxide products. Results showed the excellent conversion and selectivity for substrates in green system after 90 second at room temperature [6-12].

نویسندگان

Saeed Rayati

Department of Chemistry, K.N. Toosi University of Technology, P.O. Box ۱۶۳۱۵-۱۶۱۸, Tehran ۱۵۴۱۸, Iran

Elham Khodaei

Department of Chemistry, K.N. Toosi University of Technology, P.O. Box ۱۶۳۱۵-۱۶۱۸, Tehran ۱۵۴۱۸, Iran